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My personal top 5 would be (in no particular order)
Coldcut - 70 Minutes Of Madness
The greatest mix of all time? Possibly, and there is never a dull moment.
Sasha & Digweed - Northern Exposure
The benchmark for all prog-house and trance mixes
Pete Tong & Boy George - MoS The Annual II
Pure cheese but reminds me of some very good times
The Prodigy - The Dirtchamber Sessions Vol 1
Just love the way this sounds.
Bentley Rhythm Ace - FSUK Vol 3
Uber-fun that you can play whatever mood you are in.
Bubbling Under: GU007 by Paul Oakenfold, GU015 by Darren Emerson, Quannum Breezeblock session and FabricLice01 by James Lavelle.